Showing posts with label Operator. Show all posts
Showing posts with label Operator. Show all posts

Quantum Mechanics - Spin Angular Momentum

Two ions 1 and 2, at fixed separation, with spin angular momentum operators S1 and S2, have the interaction Hamiltonian H = −J S1·S2, where J > 0. The values of S1² and S2² are fixed at S1(S+ 1) and S2(S+ 1), respectively. Which of the following is the energy of the ground state of the system?

A. 0
B. –JS1S2
C. –J[S1(S+ 1) – S2(S+ 1)]
D. –(J/2)[(SS2)(S+ S+ 1) – S1(S1+1) – S2(S2+1)]
E. –(J/2)[(S1(S+ 1) + S2(S+ 1))/(SS2)(S+ S+ 1)]
(GR9677 #77)
Solution:

S1² ψ S1(S+ 1) ψ
S2² ψ S2(S+ 1) ψ
Si² ψ Si(Si + 1) ψ

H = −J S1·S2

Using general arithmetic equation: ab = ½ [(a + b)² − a² − b²]
H = −(J/2)[(S1 + S2)² − S1² − S2²]

Since Si² ψ Si(Si + 1) ψ
For (S1 + S2)² → replace Si with S1 + S2
→ (S1 + S2)² ψ (SS2)(SS2 + 1) ψ

H = −(J/2)[(SS2)(SS2 + 1) − S1(S+ 1) − S2(S+ 1)]

Answer: D 

Quantum Mechanics - Wave Function

If a freely moving electron is localized in space to within ∆x0 of x0, its wave function can be described by a wave packet



where f(k) is peaked around a central value k0. Which of the following is most nearly the width of the peak in k?

A. 

B.

C.

D.

E.

(GR9277 #27)
Solution:

In quantum mechanics, the momentum p = ħk and position x wave functions are Fourier transform pairs and the relation between p and x representations forms the Heisenberg uncertainty relation:

xk ≥ 1 → ∆k ≥ 1/∆x

Or, since k and are fourier variables, their localization would vary inversely.

Answer: B

Quantum Mechanics - Expectation Value

If ψ is a normalized solution of the Schrodinger equation and Q is the operator corresponding to a physical observable x and the quantity ψ*Qψ may be integrated in order to obtain the 

A. Normalization constant for ψ
B. Spatial overlap of Q with ψ
C. Mean value of x
D. Uncertainty in x
E. Time derivative of x
(GR8677 #56)
Solution:

Expectation value: 
  • The predicted mean value of the result of an experiment.
  • The average value of the measurable quantity Q (observable x) on the state ψ

Answer: C

Quantum Mechanics - Hermitian Operator

The eigenvalues of a Hermitian operator are always

A. Real
B. Imaginary
C. Degenerate
D. Linear
E. Positive
(GR0177 #27)
Solution:

The eigenvalues are always real and hence observable.
Proof:


Hermitian operator: .
So,   real

Answer: A

Quantum Mechanics - Expectation Value

The state   is linear combination of three orthonormal eigenstates of the operator corresponding to eigenvalues -1,1 and 2. What is the expectation value of    for this state?

A. 2/3
B. √(7/6)
C. 1
D. 4/3
E. (√3+2√2-1)/√6
(GR0177 #29)
Solution:

The expectation value:



Answer: C

Quantum Mechanics - Commutation Relations

The components of the orbital angular momentum operator satisfy the following commutation relations.



What is the value of the commutator ?

A.
B.
C.
D.
E.
(GR0177 #43)
Solution:

Commutator identities: [A, B] = − [B, A]

and, [BAC] = A[BC] + [BA]C 

Therefore,




 

Answer: D

Quantum Mechanics - Harmonic Oscillator

Let represent the normalized nth energy eigenstate of the one-dimensional harmonic oscillator,



If is a normalized ensemble state that can be expanded as a linear combination



of the eigenstates, what is the expectation value of the energy operator in this ensemble state?

A. 

B. 

C. 

D. 

E. 
(GR0177 #45)
Solution:

The energy eigenstates:



The expectation value:



Answer: B

Quantum Mechanics - Perturbation Theory

The raising and lowering operators for the quantum harmonic oscillator satisfy


for energy eigenstates with energy . Which of the following gives the first-order shift in the   energy level due to the perturbation



where is constant?

A.
B. 
C.
D.
E.
(GR0177 #94)
Solution:

The energy



with   and 




Raising and lowering operators:
















Answer: E