Questions 51-53
A particle of mass
m is confined to an infinitely deep square-well potential:
V(
x) = ∞,
x ≤ 0,
x ≥
a
V(
x) = 0, 0
x
a
The normalized eigenfunction, labeled by the quantum number
n, are
For any state
n, the expectation value of the momentum of the particle is
A. 0
B.
C.
D.
E.
(GR9277 #51)
Solution:
Infinitely deep square-well potential
→ there is zero probability for particle to be outside the well
→ 〈

〉= 0
If 〈

〉 ≠ 0 the particle would tend to go to the right or left and leave the well, which is impossible for infinitely deep square-well potential.
Answer: A
Alternative Answer #1:
Eigen function,
ψn =
λψn
The eigenvalue,
λ is associated with expectation value:〈Â〉= 〈
ψ | Â |
ψ〉
Since

is imaginer and
ψn is real → the eigenvalue,
λ is imaginer = not real = not observable
→ 〈

〉= 0
Alternative Answer #2: since sine and cosine are orthogonal the whole period.