Nuclear & Particle Physics - Hydrogen Spectrum

In the spectrum of Hydrogen, what is the ratio of the longest wavelength in the Lyman series (n_f  = 1) to the longest wavelength in the Balmer series (n_f  = 2)?

A. 5/27
B. 1/3
C. 4/9
D. 3/2
E. 3

(GR9677 #09)

Solution:

Rydberg formula:



λ_vac = the wavelength of the light emitted in vacuum
R_H = Rydberg constant for Hydrogen
n₁ and n₂ are integers such that n₁  n₂

For the longest wavelength take n₂ = ∞

For Lyman-radiation (n₂ = ∞ → n₁ = 1):

1/λ_L = R_H (1/1 − 0) = R_H

For Balmer-radiation (n₂ = ∞ → n₁ = 2):

1/λ_B = R_H (¼ − 0) = ¼R_H

The Ratio:

^λ_L/_λB = (¹/_RH)(^R_H/₄) = ¼ ≈ 5/27

Answer: A