Thermal Physic - Critical Isotherm

Questions 46-47.


Isotherms and coexistence curves are shown in the PV diagram above for a liquid-gas system. The dashed lines are the boundaries of the labeled regions. Which numbered curve is the critical isotherm? 

A. 1
B. 2
C. 3
D. 4
E. 5
(GR9277 #46)
Solution:

Critical isotherm (critical temperature) → dP/dV = 0
  • the derivative of the curve is zero
  • the tangent to the curve results in a horizontal line
  • the point where the vertical and horizontal dashed lines cross


Answer: B

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