Nuclear & Particle Physics - Spectroscopic Notation

In a 3S state of the helium atom, the possible values of the total electronic angular momentum quantum number are

A. 0 only
B. 1 only
C. 0 and 1 only
D. 0, 1/2, and 1
E. 0, 1, and 2
(GR9277 #31)
Solution:

Spectroscopic notation: N2s+1 Lj=l+s

  • N = the principal quantum number and will often be omitted
  • s = the total spin quantum number
  • L = the orbital angular momentum quantum number, l but is written as S, P, D, F, … for l = 0, 1, 2, 3,⋯
  • j = the total angular momentum quantum number

For 3S 
Sl = 0
3 → 3 = 2s + 1 → s = 1
j = l + s = 0 + 1 = 1

Answer: B 

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