Nuclear & Particle Physics - Hydrogen

The spacing of the rotational energy levels for the hydrogen molecule H₂ is most nearly

A. 10⁻⁹ eV
B. 10⁻³ eV
C. 10 eV
D. 10 MeV
E. 100 MeV

(GR9277 #90)

Solution:

Rotational kinetic energy: E = ^L²∕_2I
Angular momentum: L² = l(l+1)ħ² with l = 0,1,2,⋯
Moment Inertia: I = mr²

For hydrogen atom:
r = 0.529 × 10⁻¹⁰ m
m =10⁻²⁷ kg (mass of proton)
→ I = 10⁻²⁷(0.529×10⁻¹⁰)² ≈ 10⁻⁴⁷ kgm²
ħ = ^h∕_2π = ^{6.63×10−34}∕ _2(3.14) ≈ 10⁻³⁴

For l = 0 → L = 0 → E = 0
For l = 1 → L = 2ħ² → E = ^ħ²∕_I

The spacing of the rotational energy levels:
∆E = ^ħ²∕_I  − 0 = ^(10−34)2∕ _10⁻⁴⁷ = 10⁻⁶⁸⁺⁴⁷ = 10⁻²¹ J

Convert to eV: 1 eV = 1.6 × 10⁻¹⁹ J
→ ∆E = ¹⁰⁻²¹∕ _{1.6 × 10⁻¹⁹} ≈ 10⁻³ eV

Answer: B