In a Maxwell-Boltzmann system with two states of energies ε and 2ε respectively, and a degeneracy of 2 for each state, the partition function is
A. e −ε / kT
B. 2e−2ε / kT
C. 2e−3ε / kT
D. e−ε / kT + e−2ε / kT
E. 2(e−ε / kT+ e−2ε / kT)
(GR0177 #49)
Solution:
Canonical partition function: Z = Σi e−βEi
β = 1/kT
For Maxwell-Boltzmann System: Z = Σi gi e−βEi
gi = degeneracy
Thus, the partition function is
Z = 2e−βε + 2e−2βε = 2(e−ε / kT + e−2ε / kT)
Answer: E
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