An energy-level diagram of the n = 1 and n = 2 levels of atomic hydrogen (including the effect of spin-orbit coupling and relativity) is shown in the figure. Three transitions are labeled A, B, and C. Which of the transitions will be possible electric-dipole transition?
A. B only
B. C only
C. A and C only
D. B and C only
E. A, B, and C
(GR0177 #84)
Solution:
Selection rules:
1. | Principal quantum number | : | ∆n = anything |
2. | Orbital angular momentum | : | ∆l = ±1 |
3. | Magnetic quantum number | : | ∆ml = 0, ±1 |
4. | Spin | : | ∆s = 0 |
5. | Total angular momentum | : | ∆j = 0, ±1, but j = 0 ↛j = 0 |
Transition A:
l = 0 to l = 0 → ∆l = 0 → NOT ALLOWED
Transition B:
l = 1 to l = 0 → ∆l = −1 → ALLOWED
j = 3/2 to j = 1/2 → ∆j = −1 → ALLOWED
Transition C:
j = 1/2 to j = 1/2 → ∆j = 0 → ALLOWED
Answer: D
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