The wave function for identical fermions is antisymmetric under particle interchange. Which of the following is a consequence of this property?
A. Pauli exclusion principle
B. Bohr correspondence principle
C. Heisenberg uncertainty principle
D. Bose-Einstein condensation
E. Fermi's golden rule
(GR9677 #35)
Pauli Exclusion Principle: no two electrons can have exactly the same quantum number.
ms1 = ½ and ms2 = −½
Total spin quantum number, s = ½ + (−½) = 0
Multiplicity, 2 · 0 + 1 = 1 → Singlet state (antisymmetric)
Answer: A
Notes:
Singlet: 2s + 1 = 1, s = 0
Singlet state is anti-symmetric: ψ(1,2) = −ψ(2,1)
Obeys Fermi-Dirac statistics → fermion
Triplet: 2s + 1 = 3, s = 1
Triplet state is symmetric: ψ(1,2) = ψ(2,1)
Obeys Bose-Einstein statistics → bosons
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