Quantum Mechanics - Ionization Potential

Which of the following atoms has the lowest ionization potential?

A. ²He
B. ⁷14N
C. ⁸16O
D. ¹⁸40Ar
E. ⁵⁵133Cs
(GR9677 #39)
Solution:

Ionization potential: the energy required to to remove the valence (outermost) electron from an atom

It is minimum for atoms (alkali metals) which have weakly bound electrons and higher for the noble gases which have closed shells.

²He and Argon ⁸40Ar are noble gases which have a closed-shell valence electron configuration.

14N → 1s2 2s2 2p3s2 3p(2 outermost electrons, almost a full orbital)

16O → 1s2 2s2 2p64 3s2 3p(4 outermost electrons, almost a full orbital)

⁵⁵133Cs has the highest atomic number and hence a lot of electrons. The valence electron is far from the nucleus (weakly bound), thus it needs the lowest ionization potential to remove it.

Answer: E

No comments :