Nuclear & Particle Physics - Spectroscopic Notation

The configuration of three electrons is 1s2p3p has which of the following as the value of its maximum possible total angular momentum quantum number?

A. 7/2
B. 3
C. 5/2
D. 2
E. 3/2
(GR9277 #76)
Solution:

In Spectroscopic Notation, the total angular momentum quantum number is j = l + s, where
s = the total spin quantum number → 2n+1= multiplicity, the number of spin states
l = the orbital angular momentum quantum number

Since none of the electron sub-shells are filled, we add the individual angular momentum quantum number:
1s → l1 = 0, s1 = 1/2 → j1 = 1/2
2p → l2 = 1, s2 = 1/2 → j2 = 1+1/2 = 3/2
3p → l3 = 1, s3 = 1/2 → j3 = 1 + 1/2 = 3/2

The maximum possible total angular momentum quantum number j = j1 + j2 + j3 = 7/2

Answer: A

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